Screening of Chiral Diels-Alder Catalysts by Mass Spectrometric Monitoring of the Retro Reaction
- Editore:
Cuvillier Verlag
- EAN:
9783867274456
- ISBN:
3867274452
- Pagine:
- 201
- Formato:
- Paperback
- Lingua:
- Tedesco
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Descrizione Screening of Chiral Diels-Alder Catalysts by Mass Spectrometric Monitoring of the Retro Reaction
Rapid catalyst screening for enantioselective Diels-Alder reactions was accomplished by mass spectrometric monitoring of reaction intermediates of the retro-Diels-Alder reaction. Copper catalysts as well as metal-free organocatalysts were tested. Furthermore, a protocol for simultaneous screening of catalyst mixtures was developed, offering new possibilities for high-throughput catalyst development.
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